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创新型聚氨酯泡沫和基于天然纤维的复合材料在真菌生物膜作用下对挥发性有机化合物混合物的生物过滤性能。

Performance of innovative PU-foam and natural fiber-based composites for the biofiltration of a mixture of volatile organic compounds by a fungal biofilm.

机构信息

Instituto Potosino de Investigación Científica y Tecnológica A.C., División de Ciencias Ambientales, Camino a la Presa San José No. 2055, Lomas 4(a) sección, C.P. 78216, San Luis Potosí, Mexico.

出版信息

J Hazard Mater. 2012 Jan 30;201-202:202-8. doi: 10.1016/j.jhazmat.2011.11.068. Epub 2011 Nov 28.

Abstract

The performance of perlite and two innovative carriers that consist of polyurethane (PU) chemically modified with starch; and polypropylene reinforced with agave fibers was evaluated in the biofiltration of a mixture of VOCs composed of hexane, toluene and methyl-ethyl-ketone. At a total organic loading rate of 145 gCm(-3)h(-1) the elimination capacities (ECs) obtained were 145, 24 and 96 gCm(-3)h(-1) for the biofilters packed with the PU, the reinforced polypropylene, and perlite, respectively. Specific maximum biodegradation rates of the mixture, in the biofilters, were 416 mgCg(protein)(-1)  h(-1) for the PU and 63 mgCg(protein)(-1) h(-1) for perlite, which confirms the highest performance of the PU-composite. 18S rDNA analysis from the PU-biofilter revealed the presence of Fusarium solani in its sexual and asexual states, respectively. The modified PU carrier significantly reduced the start-up period of the biofilter and enhanced the EC of the VOCs. Thus, this study gives new alternatives in the field of packing materials synthesis, promoting the addition of easily biodegradable sources to enhance the performance of biofilters.

摘要

膨胀珍珠岩和两种新型载体(由化学改性淀粉的聚氨酯(PU)和由龙舌兰纤维增强的聚丙烯组成)的性能在由正己烷、甲苯和甲乙酮组成的 VOCs 混合物的生物过滤中进行了评估。在总有机负荷率为 145 gCm(-3)h(-1)的情况下,分别用填充有 PU、增强聚丙烯和膨胀珍珠岩的生物过滤器获得的去除容量(EC)为 145、24 和 96 gCm(-3)h(-1)。混合物在生物过滤器中的特定最大生物降解速率,对于 PU 分别为 416 mgCg(protein)(-1)  h(-1)和 63 mgCg(protein)(-1) h(-1),这证实了 PU 复合材料的最高性能。从 PU 生物过滤器中的 18S rDNA 分析显示,在其有性和无性状态下分别存在尖孢镰刀菌。改性的 PU 载体显著缩短了生物过滤器的启动期,并提高了 VOCs 的 EC。因此,这项研究为包装材料合成领域提供了新的选择,促进了可生物降解来源的添加,以提高生物过滤器的性能。

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