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用于处理生活污水的膜电极组件微生物燃料电池(MEA-MFC)的构想和优化。

Conception and optimization of a membrane electrode assembly microbial fuel cell (MEA-MFC) for treatment of domestic wastewater.

机构信息

National University of Singapore, Singapore.

出版信息

Water Sci Technol. 2011;64(7):1527-32. doi: 10.2166/wst.2011.067.

DOI:10.2166/wst.2011.067
PMID:22179652
Abstract

A membrane electrode assembly (MEA) for microbial fuel cells (MEA-MFC) was developed for continuous electricity production while treating domestic wastewater concurrently. It was optimized via three upgraded versions (noted α, β and γ) in terms of design (current collectors, hydrophilic separator nature) and operating conditions (hydraulic retention time, external resistance, aeration rate, recirculation). An overall rise of power by over 100% from version α to γ shows the importance of factors such as the choice of proper construction materials and prevention of short-circuits. A power of 2.5 mW was generated with a hydraulic retention time of 2.3 h when a Selemion proton exchange membrane was used as a hydrophilic separator in the MEA and 2.8 mW were attained with a reverse osmosis membrane. The MFC also showed a competitive value of internal resistance (≈40-50 Ω) as compared to the literature, especially considering its large volume (3 L). However, the operation of our system in a complete loop where the anolyte was allowed to trickle over the cathode (version γ) resulted in system failure.

摘要

针对同时处理生活污水和连续发电的需求,开发了一种用于微生物燃料电池的膜电极组件(MEA-MFC)。通过三个升级版本(α、β和γ)在设计(集流器、亲水性分离器性质)和操作条件(水力停留时间、外电阻、曝气率、循环)方面进行了优化。从版本α到γ,功率总体上升了 100%以上,这表明选择合适的结构材料和防止短路等因素非常重要。当使用 Selemion 质子交换膜作为 MEA 中的亲水性分离器时,水力停留时间为 2.3 小时,可产生 2.5 mW 的功率,而使用反渗透膜时可产生 2.8 mW 的功率。与文献相比,该 MFC 还表现出了有竞争力的内阻(≈40-50 Ω),特别是考虑到其较大的体积(3 L)。然而,我们的系统在一个完整的回路中运行,其中阳极液允许滴过阴极(版本γ),导致系统故障。

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