N-酰基-N-羧甲基-2-硝基苯胺及其类似物：一类新型的水溶性光解羧酸前体。
N-acyl-N-carboxymethyl-2-nitroaniline and its analogues: a new class of water-soluble photolabile precursor of carboxylic acids.
机构信息
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, Japan.
出版信息
Photochem Photobiol Sci. 2012 Mar;11(3):493-6. doi: 10.1039/c2pp05322e. Epub 2011 Dec 20.
PMID:22186948
Abstract
The synthesis and photochemistry of a new class of water-soluble, photolabile protecting group, the N-carboxymethyl-2-nitroanilinyl (CNA) group, are described. All three CNA-caging compounds synthesized underwent clean photochemical reaction in aqueous buffer solution to produce the intended product of acetic acid, along with the corresponding nitroso aromatic.
摘要
描述了一类新的水溶性、光不稳定保护基团，即 N-羧甲基-2-硝基苯甲酰基（CNA）基团的合成和光化学。所合成的三种 CNA-笼状化合物在水性缓冲溶液中均能进行清洁的光化学反应，生成预期的产物乙酸，以及相应的硝基亚芳基。
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