高氯酸[1,3-双（二苯基膦基）丙烷-κP,P']（1,10-菲咯啉-κN,N'）铜（I）
[1,3-Bis(diphenyl-phosphan-yl)propane-κP,P'](1,10-phenanthroline-κN,N')copper(I) perchlorate.
作者信息
Xiao Ye-Lan, Zhou Li-Li, Gao Sen, Jin Qiong-Hua, Zhang Cun-Lin
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1713-4. doi: 10.1107/S160053681104606X. Epub 2011 Nov 9.
The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis-(diphenyl-phosphan-yl)propane mol-ecule and two N atoms of a 1,10-phenanthroline ligand, with a coordination geometry that can be considered as distorted tetra-hedral. The crystal studied was twinned with a twin ratio of 0.786 (2):0.214 (2).
标题化合物[Cu(C₁₂H₈N₂)(C₂₇H₂₆P₂)]ClO₄在不对称单元中结晶，含有两个Cu(I)络合阳离子和两个高氯酸根阴离子。每个Cu(I)阳离子由一个1,3-双（二苯基膦基）丙烷分子的两个P原子和一个1,10-菲咯啉配体的两个N原子四配位，其配位几何形状可视为扭曲的四面体。所研究的晶体为孪晶，孪晶比为0.786 (2):0.214 (2)。
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