• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

二-μ-乙酸根-κO:O-双-{（乙酸根-κO,O'）双-[3-(1H-咪唑-1-基-κN)-1-苯基-丙-1-酮]镉}四水合物

Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} tetra-hydrate.

作者信息

Guo Jian-Hua

机构信息

College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1884. doi: 10.1107/S1600536811050021. Epub 2011 Nov 30.

DOI:10.1107/S1600536811050021
PMID:22199645
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238768/
Abstract

In the mol-ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa-hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-κN(3))-1-phenyl-propan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd-O distance,and the N atom of the second L ligand, forming the longer Cd-N distance, occupy axial positions with an N-Cd-O angle of 170.77 (7)°. Inter-molecular O-H⋯O hydrogen bonds exist between the lattice water mol-ecules and the acetate ions of adjacent mol-ecules, resulting in a two-dimensional supra-molecular structure.

摘要

在标题中性双核配合物[Cd₂(C₂H₃O₂)₄(C₁₂H₁₂N₂O)₄]·4H₂O的分子结构中，每个Cd(II)原子为六配位，呈现出扭曲的八面体几何构型。来自两个乙酸根离子的三个O原子和一个单齿的3-(1H-咪唑-1-基-κN³)-1-苯基-丙-1-酮(L)配体形成赤道平面，而形成较长Cd - O距离的桥连O原子和形成较长Cd - N距离的第二个L配体的N原子占据轴向位置，N - Cd - O角为170.77 (7)°。晶格水分子与相邻分子的乙酸根离子之间存在分子间O - H⋯O氢键，形成二维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c3f/3238768/76812e6c0fa6/e-67-m1884-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c3f/3238768/1ac83de5489f/e-67-m1884-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c3f/3238768/76812e6c0fa6/e-67-m1884-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c3f/3238768/1ac83de5489f/e-67-m1884-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3c3f/3238768/76812e6c0fa6/e-67-m1884-fig2.jpg

相似文献

1
Di-μ-acetato-κO:O-bis-{(acetato-κO,O')bis-[3-(1H-imidazol-1-yl-κN)-1-phenyl-propan-1-one]cadmium} tetra-hydrate.二-μ-乙酸根-κO:O-双-{（乙酸根-κO,O'）双-[3-(1H-咪唑-1-基-κN)-1-苯基-丙-1-酮]镉}四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1884. doi: 10.1107/S1600536811050021. Epub 2011 Nov 30.
2
catena-Poly[[(acetato-κO,O')(methanol-κO)cadmium(II)]-μ-[1,2-bis-(1H-benzimid-azol-2-yl)ethane]-κN:N-[(acetato-κO,O')(methanol-κO)cadmium(II)]-di-μ-chlorido].链状聚[[(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - μ - [1,2 - 双-(1H - 苯并咪唑 - 2 - 基)乙烷] - κN:N - [(乙酸根 - κO,O')(甲醇 - κO)镉(II)] - 二 - μ - 氯化物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):m578. doi: 10.1107/S1600536810014753.
3
[μ-2-(4-Hy-droxy-phen-yl)acetato]-κO:O,O';κO,O':O'-bis-{aqua-(4,4'-bi-pyridine-κN)bis-[2-(4-hy-droxy-phen-yl)acetato-κO,O']holmium(III)} mono-hydrate.[μ-2-(4-羟基苯基)乙酸根]-κO:O,O';κO,O':O'-双-{水合-(4,4'-联吡啶-κN)双-[2-(4-羟基苯基)乙酸根-κO,O']钬(III)}一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 15;67(Pt 2):m191-2. doi: 10.1107/S1600536811001115.
4
Crystal structure of bis-[(acetato-κO)(imidazolidine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-μ-imidazol-idine-2-thione-κ(4) S:S-bis-[(imidazol-id-ine-2-thione-κS)bis-(tri-phenyl-phosphane-κP)silver(I)] di-acetate aceto-nitrile disolvate tetra-hydrate.双-[(乙酸根-κO)(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二-μ-咪唑烷-2-硫酮-κ(4)S:S-双-[(咪唑烷-2-硫酮-κS)双-(三苯基膦-κP)银(I)]二乙酸乙腈溶剂合物四水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 4;72(Pt 4):444-7. doi: 10.1107/S205698901600308X. eCollection 2016 Apr 1.
5
Poly[bis-(μ(4)-acetato-κO:O:O':O')bis-(μ(3)-acetato-κO:O:O)(μ(2)-acetato-κO:O')(μ(2)-acetic acid-κO:O')di-μ-aqua-copper(II)tris-odium].聚[双（μ(4)-乙酸根-κO:O:O':O'）双（μ(3)-乙酸根-κO:O:O）（μ(2)-乙酸根-κO:O'）（μ(2)-乙酸-κO:O'）双-μ-水合铜（II）三钠]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1244. doi: 10.1107/S1600536810035683.
6
catena-Poly[[bis-[3-(1H-imidazol-1-yl)-1-phenyl-propan-1-one-κN]nickel(II)]-μ-oxalato-κO,O:O,O].链状聚[[双-[3-(1H-咪唑-1-基)-1-苯基-丙-1-酮-κN]镍(II)]-μ-草酸根-κO,O:O,O]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1832. doi: 10.1107/S1600536811049646. Epub 2011 Nov 25.
7
Tetra-kis[μ-2-(4-hy-droxy-phenyl)-acetato]-κO,O':O;κO:O,O'-bis-{aqua-(4,4'-bi-pyridine-κN)bis-[2-(4-hy-droxy-phenyl)-acetato-κO,O]neodymium(III)} monohydrate.四[μ - 2 - (4 - 羟基 - 苯基) - 乙酸根] - κO，O':O;κO:O，O'-双-{水合-(4,4'-联吡啶 - κN)双[2 - (4 - 羟基 - 苯基) - 乙酸根 - κO，O]钕(III)}一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 30;66(Pt 11):m1476-7. doi: 10.1107/S1600536810043023.
8
catena-Poly[[[(acetato-κO,O')cadmium]-μ-acetato-κO,O':O'-μ-{1,2-bis-[4-(pyridin-3-yl)pyrimidin-2-ylsulfan-yl]ethane}-κN,N] trihydrate].链状聚[[[(乙酸根-κO,O')镉]-μ-乙酸根-κO,O':O'-μ-{1,2-双-[4-(吡啶-3-基)嘧啶-2-基硫烷基]乙烷}-κN,N]三水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1740. doi: 10.1107/S1600536811046794. Epub 2011 Nov 12.
9
Bis[μ-2-(4-hy-droxy-phen-yl)acetato]-κO,O':O;κO:O,O'-bis-{aqua-(4,4'-bipyridine-κN)bis-[2-(4-hy-droxy-phen-yl)acetato-κO,O']thulium(III)} mono-hydrate.一水合双[μ-2-(4-羟基苯基)乙酸根]-κO,O':O;κO:O,O'-双-{水合-(4,4'-联吡啶-κN)双-[2-(4-羟基苯基)乙酸根-κO,O']铥(III)}
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 31;66(Pt 11):m1497. doi: 10.1107/S1600536810043898.
10
catena-Poly[[tetra-kis(μ(2)-acetato-κO:O')dicopper(II)(Cu-Cu)]-μ(2)-acetato-κO:O'-[bis-[μ(2)-3-(dimethyl-amino)propan-1-olato]-κN,O:O;κO:N,O-bis-[(tetra-hydro-furan-κO)copper(II)]]-μ(2)-acetato-κO:O'].链状聚[[四-双(μ(2)-乙酸根-κO:O')二铜(II)(铜-铜)]-μ(2)-乙酸根-κO:O'-[双-[μ(2)-3-(二甲基氨基)丙醇根]-κN,O:O;κO:N,O-双-[(四氢呋喃-κO)铜(II)]]-μ(2)-乙酸根-κO:O']
Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 9;64(Pt 9):m1139-40. doi: 10.1107/S1600536808024148.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.