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4-甲基苯甲酸-2-（4-溴苯基）-2-氧代乙酯

2-(4-Bromo-phen-yl)-2-oxoethyl 4-methyl-benzoate.

作者信息

Fun Hoong-Kun, Shahani Tara, Garudachari B, Isloor Arun M, Satyanarayan M N

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3154. doi: 10.1107/S1600536811045272. Epub 2011 Nov 2.

DOI:10.1107/S1600536811045272
PMID:22199680
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238827/
Abstract

The title compound, C(16)H(13)BrO(3), consists of a toluene ring and a bromo-benzene ring which are linked together by a 2-oxopropyl acetate group. The dihedral angle formed between the toluene and bromo-benzene rings is 80.70 (7)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

摘要

标题化合物C₁₆H₁₃BrO₃由一个甲苯环和一个溴苯环组成，它们通过一个2-氧代丙酸乙酯基团连接在一起。甲苯环和溴苯环之间形成的二面角为80.70 (7)°。在晶体中，分子间的C-H⋯O氢键将分子连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4e7/3238827/ebd2b2dfec22/e-67-o3154-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4e7/3238827/de162879c8e7/e-67-o3154-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4e7/3238827/ebd2b2dfec22/e-67-o3154-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4e7/3238827/de162879c8e7/e-67-o3154-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a4e7/3238827/ebd2b2dfec22/e-67-o3154-fig2.jpg

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A short history of SHELX.SHELX简史。
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Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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