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(E)-1-(4,4''-Difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-yl)-3-phenyl-prop-2-en-1-one.

作者信息

Betz Richard, Gerber Thomas, Hosten Eric, Samshuddin S, Narayana Badiadka, Yathirajan Hemmige S

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3159-60. doi: 10.1107/S1600536811045375. Epub 2011 Nov 2.

Abstract

The title compound, C(28)H(20)F(2)O(2), is a polysubstituted terphenyl derivative bearing a Michael system. The C=C double bond is E configured. In the crystal, C-H⋯O and C-H⋯F contacts connect the mol-ecules, forming undulating sheets that lie perpendicular to the crystallographic a axis. The shortest π-π inter-action [centroid-centroid distance = 3.7163 (7) Å] involves the para-fluoro-phenyl ring in the para position to the Michael system, and its symmetry-generated equivalent.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0966/3238831/0b05bf8af002/e-67-o3159-fig1.jpg

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