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（E）-1-（4,4''-二氟-5'-甲氧基-1,1':3',1''-三联苯-4'-基）-3-（6-甲氧基萘-2-基）丙-2-烯-1-酮

(E)-1-(4,4''-Difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-yl)-3-(6-meth-oxy-naphthalen-2-yl)prop-2-en-1-one.

作者信息

Fun Hoong-Kun, Hemamalini Madhukar, Samshuddin S, Narayana B, Sarojini B K

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3327-8. doi: 10.1107/S1600536811047660. Epub 2011 Nov 16.

DOI:10.1107/S1600536811047660
PMID:22199825
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238976/
Abstract

In the title compound, C(33)H(24)F(2)O(3), the central benzene ring makes dihedral angles of 44.71 (10), 47.80 (10) and 63.68 (9)° with the two fluoro-substituted benzene rings and the naphthalene ring system, respectively. In the crystal, mol-ecules are connected via inter-molecular C-H⋯F and C-H⋯O hydrogen bonds. Furthermore, the crystal structure is stabilized by weak C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.6816 (13) Å].

摘要

在标题化合物C(33)H(24)F(2)O(3)中，中心苯环与两个氟取代苯环和萘环系统分别形成的二面角为44.71 (10)°、47.80 (10)°和63.68 (9)°。在晶体中，分子通过分子间C-H⋯F和C-H⋯O氢键相连。此外，晶体结构通过弱C-H⋯π和π-π相互作用[质心-质心距离 = 3.6816 (13) Å]得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b54/3238976/081c35b38ae8/e-67-o3327-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b54/3238976/b2b65383e37c/e-67-o3327-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b54/3238976/081c35b38ae8/e-67-o3327-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b54/3238976/b2b65383e37c/e-67-o3327-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b54/3238976/081c35b38ae8/e-67-o3327-fig2.jpg

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