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（E）-1-（2,4-二硝基苯基）-2-[1-（2-甲氧基苯基）亚乙基]肼

(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(2-meth-oxy-phen-yl)ethyl-idene]hydrazine.

作者信息

Fun Hoong-Kun, Nilwanna Boonlerd, Jansrisewangwong Patcharaporn, Kobkeatthawin Thawanrat, Chantrapromma Suchada

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3202-3. doi: 10.1107/S1600536811045417. Epub 2011 Nov 5.

DOI:10.1107/S1600536811045417
PMID:22199722
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3238869/
Abstract

The mol-ecule of the title compound, C(15)H(14)N(4)O(5), is in an E conformation with respect to the C=N double bond and the dihedral angle between the two benzene rings is 37.83 (7)°. The ethyl-idenehydrazine plane makes dihedral angles of 4.93 (9) and 42.38 (9)° with the two benzene rings. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked by weak C-H⋯O inter-actions into chains along the c axis which are stacked along the b axis by aromatic π-π inter-actions with a centroid-centroid distance of 3.5927 (10) Å.

摘要

标题化合物C(15)H(14)N(4)O(5)的分子相对于C=N双键呈E构象，两个苯环之间的二面角为37.83 (7)°。亚乙基肼平面与两个苯环的二面角分别为4.93 (9)°和42.38 (9)°。分子内N-H⋯O氢键形成一个S(6)环模式。在晶体中，分子通过弱C-H⋯O相互作用沿c轴连接成链，这些链通过芳香π-π相互作用沿b轴堆积，质心间距为3.5927 (10) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eaa6/3238869/4a454cdccac9/e-67-o3202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eaa6/3238869/851af46734a0/e-67-o3202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eaa6/3238869/4a454cdccac9/e-67-o3202-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eaa6/3238869/851af46734a0/e-67-o3202-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/eaa6/3238869/4a454cdccac9/e-67-o3202-fig2.jpg

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