Blagus Anita, Kaitner Branko
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3252. doi: 10.1107/S1600536811046988. Epub 2011 Nov 9.
The title mol-ecule, C(32)H(24)N(2)O(2), has a crystallographically imposed inversion centre and exists in the crystal as an enol-imine tautomer. The mol-ecular structure is stabilized by two strong intra-molecular O-H⋯N hydrogen bonds. The dihedral angles between the central benzene ring and the mean planes of the phenyl substituents are 59.99 (1) and 62.79 (2)°. In the crystal, the mol-ecules are arranged into (010) layers via C-H⋯π inter-actions.
标题分子C(32)H(24)N(2)O(2)具有晶体学上的倒转中心,在晶体中以烯醇-亚胺互变异构体形式存在。分子结构通过两个强的分子内O-H⋯N氢键得以稳定。中心苯环与苯基取代基平均平面之间的二面角分别为59.99 (1)°和62.79 (2)°。在晶体中,分子通过C-H⋯π相互作用排列成(010)层。