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2-{[(4-{[(2-羟基苯基)(苯基)亚甲基]氨基}丁基)亚氨基](苯基)甲基}苯酚

2-{[(4-{[(2-Hy-droxy-phen-yl)(phen-yl)methyl-idene]amino}-but-yl)imino](phen-yl)meth-yl}phenol.

作者信息

Jamshidvand Arezoo, Kia Reza, Kargar Hadi, Tahir Muhammad Nawaz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o292. doi: 10.1107/S1600536811055905. Epub 2012 Jan 7.

DOI:10.1107/S1600536811055905
PMID:22346930
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274985/
Abstract

The asymmetric unit of the title compound, C(30)H(28)N(2)O(2), comprises half of a potential tetra-dentate Schiff base ligand; an inversion centre is situtated at the center of the butane-diamine spacer. The central methyl-ene segment of the diamine spacer is disordered over two positions with a refined site-occupancy ratio of 0.651 (7):0.349 (7). The phenyl ring and the hy-droxy-substituted benzene ring are almost perpendicular to each other, with a dihedral angle of 87.90 (8) Å. Intra-molecular O-H⋯N hydrogen bonds make S(6) ring motifs.

摘要

标题化合物C(30)H(28)N(2)O(2)的不对称单元包含一个潜在四齿席夫碱配体的一半；一个倒转中心位于丁二胺间隔基的中心。二胺间隔基的中心亚甲基片段在两个位置上无序，精修的位点占有率比为0.651 (7):0.349 (7)。苯环和羟基取代的苯环几乎相互垂直，二面角为87.90 (8) Å。分子内O-H⋯N氢键形成S(6)环模式。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8a6/3274985/6f27d500f6bd/e-68-0o292-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8a6/3274985/6f27d500f6bd/e-68-0o292-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c8a6/3274985/6f27d500f6bd/e-68-0o292-fig1.jpg

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本文引用的文献

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