Cai Mingjian
Department of Chemistry, Tangshan Normal University, Tangshan 063000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3402. doi: 10.1107/S1600536811047702. Epub 2011 Nov 23.
The title compound, C(11)H(8)Br(2)N(4), is a Schiff base obtained from 6-bromo-picolinaldehyde and 5-bromo-pyridine-3,4-diamine. The mol-ecule has an E configuration about the C=N bond and the dihedral angle between the two pyridine rings is 14.02 (1)°. The observed conformation is stabilised by an intramolecular N-H⋯N hydrogen bond. In the crystal, mol-ecules are stacked along the b axis and are linked through N-H⋯N hydrogen bonds into chains along the c axis.