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5-Bromo-N-[(E)-(6-bromo-pyridin-2-yl)methyl-idene]pyridine-3,4-diamine.

作者信息

Cai Mingjian

机构信息

Department of Chemistry, Tangshan Normal University, Tangshan 063000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3402. doi: 10.1107/S1600536811047702. Epub 2011 Nov 23.

Abstract

The title compound, C(11)H(8)Br(2)N(4), is a Schiff base obtained from 6-bromo-picolinaldehyde and 5-bromo-pyridine-3,4-diamine. The mol-ecule has an E configuration about the C=N bond and the dihedral angle between the two pyridine rings is 14.02 (1)°. The observed conformation is stabilised by an intramolecular N-H⋯N hydrogen bond. In the crystal, mol-ecules are stacked along the b axis and are linked through N-H⋯N hydrogen bonds into chains along the c axis.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3511/3239041/05986adcea4a/e-67-o3402-fig1.jpg

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