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2-[2-(2-羧基苯基)肼叉]-3-氧代-N-苯基丁酰胺

2-[2-(2-Carb-oxy-phen-yl)hydrazinyl-idene]-3-oxo-N-phenyl-butyramide.

作者信息

Dong Jinlong, Zhang Gailing, Guo Meiyu, Wu Chuan, Ren Jianguo

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3408. doi: 10.1107/S1600536811048173. Epub 2011 Nov 23.

DOI:10.1107/S1600536811048173
PMID:22199894
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3239046/
Abstract

In the title compound, C(17)H(15)N(3)O(4), the mol-ecule is in the keto-hydrazone form. Intra-molecular N-H⋯O hydrogen bonds ensure that the mol-ecule is nearly planar (r.m.s. deviation of non-H atoms is 0.098 Å), with the two benzene rings forming a dihedral angle of 10.04 (2)°. In the crystal, inversion dimers are formed via pairs of O-H⋯O hydrogen bonds involving the -CO(2)H groups.

摘要

在标题化合物C(17)H(15)N(3)O(4)中，分子呈酮腙形式。分子内N-H⋯O氢键确保分子近乎平面（非H原子的均方根偏差为0.098 Å），两个苯环形成的二面角为10.04 (2)°。在晶体中，通过涉及-CO(2)H基团的O-H⋯O氢键对形成了反演二聚体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06a0/3239046/023f0501050f/e-67-o3408-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06a0/3239046/6bd287e20b1c/e-67-o3408-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06a0/3239046/023f0501050f/e-67-o3408-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06a0/3239046/6bd287e20b1c/e-67-o3408-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06a0/3239046/023f0501050f/e-67-o3408-fig2.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
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Crystal engineering on industrial diaryl pigments using lattice energy minimizations and X-ray powder diffraction.利用晶格能量最小化和X射线粉末衍射对工业二芳基颜料进行晶体工程。
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