Department of Organic Chemistry, Kaunas University of Technology, Radvilenu pl. 19, LT-50254 Kaunas, Lithuania.
Chem Asian J. 2012 Mar 5;7(3):614-20. doi: 10.1002/asia.201100781. Epub 2011 Dec 23.
Fullerene-hydrazone dyads have been synthesized using the Confalone reaction followed by condensation with phenylhydrazines. Room-temperature xerographic time-of-flight, ionization potential, and cyclic voltammetry measurements indicate that these narrow-band-gap (E(g)<1.5 eV), ambipolar charge-transporting dyads with balanced hole- and electron mobilities, which operate in air, are attractive materials for various optoelectronic applications.
富勒烯酰腙二聚体已通过 Confalone 反应合成,然后与苯肼缩合。室温 Xerographic 飞行时间、电离势和循环伏安法测量表明,这些具有窄带隙(E(g)<1.5 eV)、空穴和电子迁移率平衡的双极电荷传输二聚体,在空气中工作,是各种光电应用的有吸引力的材料。