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链状聚[[[水合-(1,10-菲咯啉)锰(II)]-μ-金刚烷-1,3-二羧酸根]一水合物]

catena-Poly[[[aqua-(1,10-phenanthro-line)manganese(II)]-μ-adamantane-1,3-dicarboxyl-ato] monohydrate].

作者信息

Liu Jian-Qiang, Huang Yun-Sheng

机构信息

Guangdong Medical College, School of Pharmacy, Dongguan 523808, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1541-2. doi: 10.1107/S1600536811041900. Epub 2011 Oct 12.

DOI:10.1107/S1600536811041900
PMID:22219785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3246965/
Abstract

In the title coordination polymer, {[Mn(C(12)H(14)O(4))(C(12)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) atom has a highly distorted cis-MnN(2)O(4) octa-hedral geometry arising from its coordination by a bidentate phenanthroline ligand, a water mol-ecule and monodentate and bidentate adamantane-1,3-dicarboxyl-ate dianions. The bridging dianion leads to [001] chains in the crystal. The chains are linked by O-H⋯O hydrogen bonds, involving both the coordinated and uncoordinated water mol-ecules, thereby forming a two-dimensional network.

摘要

在标题配位聚合物{[Mn(C₁₂H₁₄O₄)(C₁₂H₈N₂)(H₂O)]·H₂O}ₙ中，Mn(II)原子具有高度扭曲的顺式-MnN₂O₄八面体几何构型，这是由于它通过双齿菲咯啉配体、一个水分子以及单齿和双齿金刚烷-1,3-二羧酸二阴离子进行配位所致。桥连二阴离子在晶体中形成[001]链。这些链通过O-H⋯O氢键相连，涉及配位水分子和未配位水分子，从而形成二维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53ea/3246965/f1b1c38c0002/e-67-m1541-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53ea/3246965/25071b5be144/e-67-m1541-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53ea/3246965/f1b1c38c0002/e-67-m1541-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53ea/3246965/25071b5be144/e-67-m1541-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/53ea/3246965/f1b1c38c0002/e-67-m1541-fig2.jpg

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