• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

五羰基-1κC,2κC-[(二苯基磷酰基)二苯基膦-1κP]-μ-乙烷-1,2-二硫醇合-1:2κS,S':S,S'-二铁(I)(铁-铁)

Penta-carbonyl-1κC,2κC-[(diphenyl-phosphor-yl)diphenyl-phosphane-1κP]-μ-ethane-1,2-dithiol-ato-1:2κS,S':S,S'-diiron(I)(Fe-Fe).

作者信息

Liu Xu-Feng, Yu Xiao-Yong

机构信息

Department of Chemical Engineering, Ningbo University of Technology, Ningbo 315016, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1552. doi: 10.1107/S1600536811042139. Epub 2011 Oct 22.

DOI:10.1107/S1600536811042139
PMID:22219793
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3246973/
Abstract

The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], con-tains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph(2)PP(O)Ph(2)]. Both Fe-atom geometries could be described as grossly distorted octa-hedral and the Ph(2)PP(O)Ph(2) ligand lies trans to the Fe⋯Fe link.

摘要

双核标题化合物[Fe₂(C₂H₄S₂)(C₂₄H₂₀OP₂)(CO)₅]或(μ - SCH₂CH₂S - μ)Fe₂(CO)₅[Ph₂PP(O)Ph₂]包含一个蝶形的Fe₂S₂核心，其中Fe⋯Fe间距为2.5275 (6) Å。其中一个铁原子还与三个羰基配体配位，另一个与两个羰基配体和一个膦配体[Ph₂PP(O)Ph₂]配位。两个铁原子的几何构型都可描述为严重扭曲的八面体，且Ph₂PP(O)Ph₂配体位于Fe⋯Fe键的反位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab29/3246973/ea54e8aa28f0/e-67-m1552-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab29/3246973/5228bd43b773/e-67-m1552-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab29/3246973/ea54e8aa28f0/e-67-m1552-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab29/3246973/5228bd43b773/e-67-m1552-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ab29/3246973/ea54e8aa28f0/e-67-m1552-fig2.jpg

相似文献

1
Penta-carbonyl-1κC,2κC-[(diphenyl-phosphor-yl)diphenyl-phosphane-1κP]-μ-ethane-1,2-dithiol-ato-1:2κS,S':S,S'-diiron(I)(Fe-Fe).五羰基-1κC,2κC-[(二苯基磷酰基)二苯基膦-1κP]-μ-乙烷-1,2-二硫醇合-1:2κS,S':S,S'-二铁(I)(铁-铁)
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1552. doi: 10.1107/S1600536811042139. Epub 2011 Oct 22.
2
Penta-carbonyl-1κC,2κC-(μ-pyrazine-2,3-dithiol-ato-1:2κS,S':S,S')(trimethyl-phosphane-1κP)diiron(I)(Fe-Fe).五羰基-1κC,2κC-(μ-吡嗪-2,3-二硫醇根-1:2κS,S':S,S')(三甲基膦-1κP)二铁(I)(铁-铁)
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1750. doi: 10.1107/S1600536811046770. Epub 2011 Nov 12.
3
[1,2-Bis(diphenyl-phosphan-yl)ethane-2κP,P']tetra-carbonyl-1κC,2κC-(μ-2-cyclo-pentyl-2-aza-propane-1,3-dithiol-ato-1:2κS,S':S,S')diiron(II)(Fe-Fe).[1,2-双（二苯基膦基）乙烷-2κP，P']四羰基-1κC，2κC-（μ-2-环戊基-2-氮杂丙烷-1,3-二硫醇-1:2κS，S':S，S'）二铁（II）（铁-铁）
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1500-1. doi: 10.1107/S1600536811040347. Epub 2011 Oct 8.
4
Penta-carbonyl-1κC,2κC-(ferrocenyl-diphenyl-phosphine-1κP)[μ-2-(4-methyl-phen-yl)-2-aza-propane-1,3-dithiol-ato-1:2κS,S':S,S']diiron(I)(Fe-Fe).五羰基-1κC,2κC-（二茂铁基二苯基膦-1κP）[μ-2-（4-甲基苯基）-2-氮杂丙烷-1,3-二硫醇根合-1:2κS,S':S,S']二铁（I）（铁-铁）
Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 18;64(Pt 11):m1423. doi: 10.1107/S1600536808032698.
5
Penta-carbonyl-1κC,2κC-(4-iodo-phenyl isocyanide-1κC)(μ-propane-1,3-dithiol-ato-1:2κS,S':S,S')iron(I)(Fe-Fe).五羰基-1κC,2κC-(4-碘苯基异腈-1κC)(μ-丙烷-1,3-二硫醇根合-1:2κS,S':S,S')铁(I)(Fe-Fe)
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1753-4. doi: 10.1107/S1600536811047088. Epub 2011 Nov 12.
6
A trinuclear Fe-Fe-Ni complex formed by ligand reshuffling.通过配体重排形成的三核铁-铁-镍配合物。
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m766-7. doi: 10.1107/S1600536811017892. Epub 2011 May 20.
7
μ-Propane-1,3-dithiol-ato-κS,S':S,S'-bis-[dicarbon-yl(triphenyl-phosphane-κP)iron(II)](Fe-Fe).μ-丙烷-1,3-二硫醇根合-κS,S':S,S'-双[二羰基（三苯基膦-κP）铁（II）]（铁-铁）
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1502. doi: 10.1107/S1600536811040621. Epub 2011 Oct 8.
8
Dicarbon-yl(pyrazine-1,3-dithiol-ato-κS,S')bis-(trimethyl-phosphane-κP)iron(II).二羰基（吡嗪-1,3-二硫醇根合-κS,S'）双（三甲基膦-κP）铁（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1790. doi: 10.1107/S1600536811048574. Epub 2011 Nov 19.
9
Bis[1,2-bis-(eth-oxy-carbon-yl)ethene-1,2-dithiol-ato-κ(2) S,S']bis-(η(5)-penta-methyl-cyclo-penta-dien-yl)tetra-μ3-sulfido-diiron(IV)diiron(III)(3 Fe-Fe).双[1,2-双（乙氧基羰基）乙烯-1,2-二硫醇合-κ(2) S,S']双（η(5)-五甲基环戊二烯基）四μ3-硫代二铁（IV）二铁（III）（3个铁-铁）
Acta Crystallogr Sect E Struct Rep Online. 2013 Mar 2;69(Pt 4):m181. doi: 10.1107/S1600536813005564. Print 2013 Apr 1.
10
A triclinic polymorph of bis-(μ(2)-ethane-thiol-ato)-1:2κS:S;3:4κS:S-(μ(4)-disulfido-1:2:3:4κS:S:S':S')tetra-kis-[tricarbonyl-iron(II)](2 Fe-Fe).双（μ(2)-乙硫醇根合）-1:2κS:S；3:4κS:S-（μ(4)-二硫代-1:2:3:4κS:S:S':S'）四-双-[三羰基铁（II）]（2个铁-铁）的三斜多晶型物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m752-3. doi: 10.1107/S1600536811017405. Epub 2011 May 14.

本文引用的文献

1
Preparation, facile deprotonation, and rapid H/D exchange of the mu-hydride diiron model complexes of the [FeFe]-hydrogenase containing a pendant amine in a chelating diphosphine ligand.具有支链胺螯合双膦配体的 [FeFe]-氢化酶的 μ-氢化物二铁模型配合物的制备、易脱质子化和快速 H/D 交换。
Inorg Chem. 2009 Dec 21;48(24):11551-8. doi: 10.1021/ic901154m.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.