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4-甲氧基-2-硝基-4'-(三氟甲基)联苯

4-Meth-oxy-2-nitro-4'-(trifluoro-meth-yl)biphen-yl.

作者信息

Hou Yan-Jun, Li Xin-Min, Chu Wen-Yi, Sun Zhi-Zhong

机构信息

College of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o2915. doi: 10.1107/S1600536811039092. Epub 2011 Oct 12.

DOI:10.1107/S1600536811039092
PMID:22219947
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3247329/
Abstract

The title compound, C(14)H(10)F(3)NO(3), was prepared by a palladium-catalysed Suzuki-Miyaura coupling reaction. The dihedral angle between the nitro group and its parent benzene ring is 66.85 (19)° while the dihedral angle between the two benzene rings is 49.98 (9)°. The CF(3) group is disordered over two sets of sites with occupancies of 0.457 (8) and 0.543 (8).

摘要

标题化合物C(14)H(10)F(3)NO(3)通过钯催化的铃木-宫浦偶联反应制备。硝基与其母体苯环之间的二面角为66.85 (19)°，而两个苯环之间的二面角为49.98 (9)°。CF(3)基团在两组位置上无序分布，占有率分别为0.457 (8)和0.543 (8)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4765/3247329/fe3d57faf95d/e-67-o2915-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4765/3247329/fe3d57faf95d/e-67-o2915-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4765/3247329/fe3d57faf95d/e-67-o2915-fig1.jpg

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本文引用的文献

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