Fan Zheng, Huang Yan-Lan, Wang Zhao, Guo Han-Qi, Shan Shang
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o3011. doi: 10.1107/S1600536811042140. Epub 2011 Oct 22.
The title compound, C(16)H(16)N(2)OS(2), was obtained from a condensation reaction of benzyl dithio-carbazate and 4-meth-oxy-benzaldehyde. In the mol-ecule, the meth-oxy-phenyl ring and dithio-carbazate fragment are located on opposite sides of the C=N double bond, showing an E configuration. The dithio-carbazate fragment is approximately planar (r.m.s. deviation = 0.0052 Å); its mean plane is oriented at dihedral angles of 8.19 (15) and 85.70 (13)°, respectively, to the meth-oxy-phenyl and phenyl rings. Inter-molecular N-H⋯S hydrogen bonds and weak C-H⋯π inter-actions are observed in the crystal structure.
标题化合物C(16)H(16)N(2)OS(2)是由苄基二硫代氨基脲与4-甲氧基苯甲醛经缩合反应制得。在分子中，甲氧基苯环和二硫代氨基脲片段位于C=N双键的两侧，呈E构型。二硫代氨基脲片段近似平面（均方根偏差 = 0.0052 Å）；其平均平面与甲氧基苯环和苯环的二面角分别为8.19 (15)°和85.70 (13)°。在晶体结构中观察到分子间N-H⋯S氢键和弱C-H⋯π相互作用。
