Wei Ang Chee, Ali Mohamed Ashraf, Ismail Rusli, Hemamalini Madhukar, Fun Hoong-Kun
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):o3124. doi: 10.1107/S1600536811044515. Epub 2011 Oct 29.
In the title compound, C(27)H(20)BrNO(3), the pyrrolidine ring adopts a half-chair conformation, while the other five-membered rings adopt flattened envelope conformations with the spiro C atoms as the flap atoms. An intra-molecular C-H⋯O hydrogen bond occurs, generating an S(6) ring. In the crystal, mol-ecules are connected via weak C-H⋯O hydrogen bonds, forming chains along the c axis.
在标题化合物C(27)H(20)BrNO(3)中,吡咯烷环呈半椅式构象,而其他五元环则以螺碳原子作为瓣原子呈扁平信封式构象。存在分子内C-H⋯O氢键,形成一个S(6)环。在晶体中,分子通过弱C-H⋯O氢键相连,沿c轴形成链状结构。