State Key Laboratory of Optoelectronic Materials and Technologies, School of Physics and Engineering, Sun Yat-sen University, Guangzhou, 510275, PR China.
Chem Soc Rev. 2012 Mar 21;41(6):2382-94. doi: 10.1039/c2cs15269j. Epub 2012 Jan 5.
This critical review tersely and concisely reviews the recent development of the polymer electrolyte membranes and the relationship between their properties and affecting factors like operation temperature. In the first section, the advantages and shortcomings of the corresponding polymer electrolyte membrane fuel cells are analyzed. Then, the limitations of Nafion membranes and their alternatives to large-scale commercial applications are discussed. Secondly, the concepts and approaches of the alternative proton exchange membranes for low temperature and high temperature fuel cells are described. The highlights of the current scientific achievements are given for various aspects of approaches. Thirdly, the progress of anion exchange membranes is presented. Finally, the perspectives of future trends on polymer electrolyte membranes for different applications are commented on (400 references).
这篇评论简明扼要地回顾了聚合物电解质膜的最新发展，以及它们的性能与操作温度等影响因素之间的关系。在第一部分中，分析了相应的聚合物电解质膜燃料电池的优缺点。然后，讨论了 Nafion 膜的局限性及其在大规模商业应用中的替代品。其次，介绍了低温和高温燃料电池用质子交换膜的替代概念和方法。对于各种方法的各个方面，给出了当前科学成果的要点。第三，介绍了阴离子交换膜的进展。最后，对不同应用领域的聚合物电解质膜未来发展趋势进行了展望（参考文献 400 篇）。
