SnCl2 催化的选择性原子经济性亚胺 Diels-Alder 反应：2-(1H-吡咯并[2,3-b]吡啶-3-基)喹啉的合成。
SnCl2-catalyzed selective atom economic imino Diels-Alder reaction: synthesis of 2-(1H-pyrrolo[2,3-b]pyridin-3-yl)quinolines.
机构信息
Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai, 625 021, India.
出版信息
J Org Chem. 2012 Feb 3;77(3):1468-76. doi: 10.1021/jo202256z. Epub 2012 Jan 25.
PMID:22229784
Abstract
The synthesis of 2-(1H-pyrrolo[2,3-b]pyridin-3-yl)quinolines by a SnCl(2)-catalyzed multicomponent reaction has been described. The reaction proceeds chemo- and regioselectively in an atom-economic way, generating a library of 24 quinoline derivatives.
摘要
已描述了通过 SnCl(2)-催化的多组分反应合成 2-(1H-吡咯并[2,3-b]吡啶-3-基)喹啉。该反应以原子经济性的方式进行化学和区域选择性地反应，生成了 24 种喹啉衍生物库。
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