Chemical Resources Laboratory, Tokyo Institute of Technology, 4259-R1-3 Nagatsuta, Yokohama 226-8503, Japan.
Chem Commun (Camb). 2012 Feb 18;48(15):2125-7. doi: 10.1039/c2cc16063c. Epub 2012 Jan 13.
[{Ni(dmpe)}(2)(μ-SiHPh(2))(2)] (dmpe = 1,2-bis(dimethylphosphino)ethane) reacted with PhC≡CPh to yield fluorescent 1,2-bis{(E)-1,2-diphenylethenyl}-1,1,2,2-tetraphenyldisilane via addition of the Si-H bond of the ligand to the alkyne and subsequent coupling of the tertiary silyl ligands forming the Si-Si bond.
[{Ni(dmpe)}(2)(μ-SiHPh(2))(2)]（dmpe=1,2-双（二甲基膦基）乙烷）与 PhC≡CPh 反应，通过配体的 Si-H 键加成到炔烃上，并随后通过三甲基硅烷基配体形成 Si-Si 键偶联，生成了荧光 1,2-双{（E）-1,2-二苯乙烯基}-1,1,2,2-四苯二硅烷。
