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[仿刺参无机元素的主成分分析与聚类分析]

[Principal component analysis and cluster analysis of inorganic elements in sea cucumber Apostichopus japonicus].

作者信息

Liu Xiao-Fang, Xue Chang-Hu, Wang Yu-Ming, Li Zhao-Jie, Xue Yong, Xu Jie

机构信息

College of Food Science and Technology, Ocean University of China, Qingdao 266003, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2011 Nov;31(11):3119-22.

Abstract

The present study is to investigate the feasibility of multi-elements analysis in determination of the geographical origin of sea cucumber Apostichopus japonicus, and to make choice of the effective tracers in sea cucumber Apostichopus japonicus geographical origin assessment. The content of the elements such as Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, Hg and Pb in sea cucumber Apostichopus japonicus samples from seven places of geographical origin were determined by means of ICP-MS. The results were used for the development of elements database. Cluster analysis(CA) and principal component analysis (PCA) were applied to differentiate the sea cucumber Apostichopus japonicus geographical origin. Three principal components which accounted for over 89% of the total variance were extracted from the standardized data. The results of Q-type cluster analysis showed that the 26 samples could be clustered reasonably into five groups, the classification results were significantly associated with the marine distribution of the sea cucumber Apostichopus japonicus samples. The CA and PCA were the effective methods for elements analysis of sea cucumber Apostichopus japonicus samples. The content of the mineral elements in sea cucumber Apostichopus japonicus samples was good chemical descriptors for differentiating their geographical origins.

摘要

本研究旨在探讨多元素分析在确定刺参地理来源中的可行性,并选择刺参地理来源评估中的有效示踪剂。采用电感耦合等离子体质谱法(ICP-MS)测定了来自七个地理来源地的刺参样品中铝、钒、铬、锰、铁、钴、镍、铜、锌、砷、硒、钼、镉、汞和铅等元素的含量。这些结果用于建立元素数据库。应用聚类分析(CA)和主成分分析(PCA)来区分刺参的地理来源。从标准化数据中提取了占总方差89%以上的三个主成分。Q型聚类分析结果表明,26个样品可合理地聚为五组,分类结果与刺参样品的海洋分布显著相关。CA和PCA是刺参样品元素分析的有效方法。刺参样品中矿物元素的含量是区分其地理来源的良好化学描述符。

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