两种铁催化剂优于一种：一种通用且便捷的还原芳香族和脂肪族伯酰胺的方法。 - Suppr

Suppr

超能文献

Two iron catalysts are better than one: a general and convenient reduction of aromatic and aliphatic primary amides.

作者信息

Das Shoubhik, Wendt Bianca, Möller Konstanze, Junge Kathrin, Beller Matthias

机构信息

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.

出版信息

Angew Chem Int Ed Engl. 2012 Feb 13;51(7):1662-6. doi: 10.1002/anie.201108155. Epub 2012 Jan 13.

DOI:10.1002/anie.201108155

PMID:22246789

Abstract

摘要

相似文献

Two iron catalysts are better than one: a general and convenient reduction of aromatic and aliphatic primary amides.两种铁催化剂优于一种：一种通用且便捷的还原芳香族和脂肪族伯酰胺的方法。

Angew Chem Int Ed Engl. 2012 Feb 13;51(7):1662-6. doi: 10.1002/anie.201108155. Epub 2012 Jan 13.

Amide bond formation through iron-catalyzed oxidative amidation of tertiary amines with anhydrides.通过铁催化的叔胺与酸酐的氧化酰胺化反应形成酰胺键。

J Org Chem. 2013 Jun 7;78(11):5638-46. doi: 10.1021/jo400804p. Epub 2013 May 23.

Chemoselective C-H bond activation: ligand and solvent free iron-catalyzed oxidative C-C cross-coupling of tertiary amines with terminal alkynes. Reaction scope and mechanism.化学选择性碳氢键活化：无配体和无溶剂的铁催化叔胺与末端炔烃的氧化碳-碳交叉偶联反应。反应范围及机理

Org Lett. 2009 Apr 16;11(8):1701-4. doi: 10.1021/ol9002509.

Zinc-catalyzed chemoselective reduction of tertiary and secondary amides to amines.锌催化的三级和二级酰胺的选择性还原胺化反应。

Chemistry. 2011 Oct 17;17(43):12186-92. doi: 10.1002/chem.201101143. Epub 2011 Sep 13.

A convenient and general iron-catalyzed reduction of amides to amines.一种便捷通用的铁催化酰胺还原为胺的方法。

Angew Chem Int Ed Engl. 2009;48(50):9507-10. doi: 10.1002/anie.200904677.

Dynamic kinetic resolution in the asymmetric synthesis of beta-amino acids by organocatalytic reduction of enamines with trichlorosilane.通过三氯硅烷对烯胺进行有机催化还原实现β-氨基酸不对称合成中的动态动力学拆分

Chemistry. 2008;14(27):8082-5. doi: 10.1002/chem.200801244.

NHC-iron-catalyzed aerobic oxidative aromatic esterification of aldehydes using boronic acids.NHC-铁催化的醛与硼酸的有氧氧化芳香酯化反应。

Org Lett. 2010 Jun 18;12(12):2686-9. doi: 10.1021/ol100302e.

Ruthenium-catalyzed oxidation of alcohols into amides.钌催化醇氧化生成酰胺。

Org Lett. 2009 Jun 18;11(12):2667-70. doi: 10.1021/ol900723v.

An efficient method to convert lactams and amides into 2,2-dialkylated amines.一种将内酰胺和酰胺转化为2,2-二烷基化胺的有效方法。

Org Lett. 2008 Apr 3;10(7):1417-20. doi: 10.1021/ol800145h. Epub 2008 Mar 4.

Reductive and catalytic monoalkylation of primary amines using nitriles as an alkylating reagent.使用腈作为烷基化试剂对伯胺进行还原催化单烷基化反应。

Org Lett. 2004 Dec 23;6(26):4977-80. doi: 10.1021/ol047871o.

引用本文的文献

Simple Cobalt Nanoparticle-Catalyzed Reductive Amination for Selective Synthesis of a Broad Range of Primary Amines.简单钴纳米颗粒催化的还原胺化反应用于选择性合成多种伯胺。

Molecules. 2025 Jul 23;30(15):3089. doi: 10.3390/molecules30153089.

Unveiling the Roles of Pt and CeO during Solvent-Free Amide Hydrogenation Utilizing Photoelectron Photoionization Coincidence Spectroscopy.利用光电子光离子符合光谱揭示Pt和CeO在无溶剂酰胺加氢反应中的作用。

ACS Catal. 2025 Apr 2;15(8):6216-6225. doi: 10.1021/acscatal.4c07955. eCollection 2025 Apr 18.

Recent Advances in Catalytic Systems for the Reduction of Aromatic and Aliphatic Nitrile Compounds to Amines.用于将芳香族和脂肪族腈化合物还原为胺的催化体系的最新进展

Comb Chem High Throughput Screen. 2025;28(3):392-416. doi: 10.2174/0113862073284975240324091848.

Ferrocenophanium Stability and Catalysis.费罗琴铵的稳定性和催化作用。

Molecules. 2023 Mar 17;28(6):2729. doi: 10.3390/molecules28062729.

Mild Divergent Semireductive Transformations of Secondary and Tertiary Amides via Zirconocene Hydride Catalysis.锆烷氢化物催化的仲、叔酰胺的温和发散半还原转化。

J Am Chem Soc. 2023 Mar 8;145(9):4921-4927. doi: 10.1021/jacs.2c11786. Epub 2023 Feb 21.

Nanoparticles and single atoms of cobalt synergistically enabled low-temperature reductive amination of carbonyl compounds.纳米颗粒与钴单原子协同作用实现了羰基化合物的低温还原胺化反应。

Chem Sci. 2022 Jul 8;13(31):9047-9055. doi: 10.1039/d2sc01596j. eCollection 2022 Aug 10.

Transition metal-free catalytic reduction of primary amides using an abnormal NHC based potassium complex: integrating nucleophilicity with Lewis acidic activation.使用基于异常氮杂环卡宾的钾配合物对伯酰胺进行无过渡金属催化还原：将亲核性与路易斯酸活化相结合。

Chem Sci. 2019 Dec 27;11(7):1848-1854. doi: 10.1039/c9sc05953a.

Selective C-N σ Bond Cleavage in Azetidinyl Amides under Transition Metal-Free Conditions.在无过渡金属条件下，氮杂环丁烷酰胺中的选择性 C-N σ 键断裂。

Molecules. 2019 Jan 28;24(3):459. doi: 10.3390/molecules24030459.

Selective Double Addition Reaction of an E‒H Bond (E = Si, B) to a C≡N Triple Bond of Organonitriles.有机腈中 E-H 键（E=Si，B）与 C≡N 三键的选择性双重加成反应。

Molecules. 2018 Oct 25;23(11):2769. doi: 10.3390/molecules23112769.

Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.使用一种结构明确的锰- PNN钳形配合物将酰胺高效选择性氢化为醇类和胺类。

Chem Sci. 2017 May 1;8(5):3576-3585. doi: 10.1039/c7sc00138j. Epub 2017 Mar 8.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验