Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, China.
Adv Mater. 2012 Feb 14;24(7):957-61. doi: 10.1002/adma.201103927. Epub 2012 Jan 17.
A novel n-type small molecule FFI-1 was synthesized as the electron acceptor to replace PCBM in solution-processed organic BHJ solar cells. Its LUMO level (around -3.5 eV) both matches the work function of the cathode and increases V(OC) of the devices, making it a promising acceptor candidate. With P3HT: FFI-1 (1:2 w/w) as active layer and LiF/Al as the cathode, the best power conversion efficiency (PCE) reaches 1.86%.
一种新型的 n 型小分子 FFI-1 被合成出来作为电子受体，以替代溶液处理的有机 BHJ 太阳能电池中的 PCBM。其 LUMO 能级（约-3.5 eV）与阴极的功函数相匹配，并提高了器件的开路电压（V(OC)），使其成为一种很有前途的受体候选材料。以 P3HT：FFI-1（1:2 w/w）作为活性层，LiF/Al 作为阴极，最佳的功率转换效率（PCE）达到 1.86%。
