The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
J Am Chem Soc. 2012 Feb 15;134(6):2914-7. doi: 10.1021/ja211410x. Epub 2012 Feb 1.
Subtle noncovalent forces such as π-π interactions play an import role in the folding of biological macromolecules such as DNA and proteins. We describe here a system where such interactions on the outside of a molecular capsule trigger a selective change of its structure as a self-assembled receptor.
微妙的非共价相互作用力，如π-π 相互作用，在 DNA 和蛋白质等生物大分子的折叠中起着重要作用。我们在这里描述了一个系统，其中分子胶囊外部的这种相互作用触发了其作为自组装受体的结构的选择性变化。
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