一种通过π-π堆积和独特的硼酸模板化氢键相互作用稳定的并排排列的聚咪唑三脚架线圈超分子组装体。
A supramolecular assembly of side-by-side polyimidazole tripod coils stabilized by pi-pi stacking and unique boric acid templated hydrogen bonding interactions.
作者信息
Cheruzel Lionel E, Mashuta Mark S, Buchanan Robert M
机构信息
Department of Chemistry, University of Louisville, 2320 S. Brook Street, Louisville, Kentucky 40292, USA.
出版信息
Chem Commun (Camb). 2005 May 7(17):2223-5. doi: 10.1039/b419040h. Epub 2005 Mar 11.
DOI:10.1039/b419040h
PMID:15856103
Abstract
The self assembly of (bis(1-methyl-imidazol-2-yl)methyl)(1-methyl-4-nitroimidazol-2-yl)methyl)amine and boric acid results in a supramolecular structure containing bundled antiparallel imidazole-boric acid helices and boric acid filled one-dimensional channels.
摘要
（双（1-甲基-咪唑-2-基）甲基）（1-甲基-4-硝基咪唑-2-基）甲基）胺与硼酸的自组装形成了一种超分子结构，该结构包含成束的反平行咪唑-硼酸螺旋以及填充有硼酸的一维通道。
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