Department of Physics, Ariel University Center of Samaria, Post Office Box 3, Ariel 40700, Israel.
Langmuir. 2012 Feb 21;28(7):3460-4. doi: 10.1021/la204424n. Epub 2012 Feb 8.
Physical mechanisms of Cassie-Wenzel wetting transitions are discussed. The origin of the potential barrier separating the Cassie and Wenzel wetting states is clarified. It may contain contributions originating from the filling of hydrophobic pores and displacement of the triple line along the smooth portions of the relief. One- and two-dimensional scenarios of wetting transitions are considered. We demonstrate that the contribution to the potential barrier because of the displacement of the triple line is not negligible in both cases.
讨论了 Cassie-Wenzel 润湿转变的物理机制。澄清了分离 Cassie 和 Wenzel 润湿状态的势垒的起源。它可能包含源自疏水孔填充和三相接触线沿着起伏平滑部分的位移的贡献。考虑了润湿转变的一维和二维情况。我们证明,在这两种情况下,由于三相接触线的位移而对势垒的贡献都不可忽略。