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超疏水氮化硼纳米管不锈钢网表面上的液滴撞击动力学

Droplet impact dynamics on the surface of super-hydrophobic BNNTs stainless steel mesh.

作者信息

Zhang Lie, Feng Yongbao, Li Liang, Li Shuzhi, Yuan Bo, Han Xiaoxia, He Zhenxin

机构信息

Rocket Force University of Engineering, Xi'an, 710025, Shaanxi, China.

出版信息

Sci Rep. 2024 Nov 12;14(1):27695. doi: 10.1038/s41598-024-75825-z.

Abstract

The 'gas‒liquid‒solid' mechanism annealing method was used to create a superhydrophobic boron nitride nanotube (BNNT) stainless steel mesh in a tube furnace at 1250 °C in an NH environment. Fe powder was used as a catalyst, and B:BO = 4:1 was used as the raw material. The water droplets on the surface of the superhydrophobic material had a contact angle of approximately 150° and a slide angle of approximately 3°. By using molecular dynamics (MD) simulation technology, a three-dimensional braided physical model of nanodroplets and superhydrophobic BNNT mesh surfaces with the same contact angle and rolling angle was prepared via the function weaving method. The Weber number (We) was used as the entrance point to establish the relationship between macroscale experimental studies and nanoscale MD simulation analysis on the basis of these efforts. A study was conducted on the dynamic behaviour of droplets impacting a superhydrophobic BNNT filter surface. We suggest that the wettability, substrate structure, and impact velocity are connected to the impact dynamic behaviour of droplets on the basis of the data obtained at various scales. The findings demonstrate that when the droplet impact velocity increases, several droplet phenomena-such as impact-rebound, impact-spread-rebound, and impact-spread-breaking-polymerisation-spatter-appear on the substrate surface sequentially. The mechanism of impact behaviour at various scales is explained in light of these events. Furthermore, a better theoretical model is proposed to assess the droplet wetting transition at the nanoscale. This model accurately predicts the boundary Weber number that starts the wetting transition. Moreover, the connections among the impact velocity, spreading diameter, and contact time (or We) are examined. The tendencies found via MD simulations match the outcomes of the experiments. Our discoveries and outcomes broaden our understanding of how droplet impact affects the dynamic behaviour of superhydrophobic surfaces. A scientific foundation for examining the dynamic behaviour of droplets is provided by combining simulations and experiments.

摘要

采用“气-液-固”机制退火法,在管式炉中于1250℃的NH环境下制备超疏水氮化硼纳米管(BNNT)不锈钢网。以铁粉为催化剂,以B:BO = 4:1为原料。超疏水材料表面的水滴接触角约为150°,滑动角约为3°。利用分子动力学(MD)模拟技术,通过函数编织法制备了具有相同接触角和滚动角的纳米液滴与超疏水BNNT网表面的三维编织物理模型。在此基础上,以韦伯数(We)为切入点,建立了宏观实验研究与纳米尺度MD模拟分析之间的关系。对液滴撞击超疏水BNNT过滤器表面的动态行为进行了研究。基于在不同尺度上获得的数据,我们认为润湿性、基底结构和撞击速度与液滴的撞击动态行为有关。研究结果表明,当液滴撞击速度增加时,基底表面依次出现几种液滴现象,如撞击反弹、撞击铺展反弹、撞击铺展破碎聚合飞溅。根据这些现象解释了不同尺度下的撞击行为机制。此外,还提出了一个更好的理论模型来评估纳米尺度下的液滴润湿转变。该模型准确地预测了开始润湿转变的边界韦伯数。此外,还研究了撞击速度、铺展直径和接触时间(或We)之间的关系。通过MD模拟发现的趋势与实验结果相符。我们的发现和结果拓宽了我们对液滴撞击如何影响超疏水表面动态行为的理解。通过结合模拟和实验,为研究液滴的动态行为提供了科学依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d445/11557963/4384e2558274/41598_2024_75825_Fig1_HTML.jpg

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