Department of Chemistry, University of California Berkeley, Berkeley, CA 94720-1460, USA.
Angew Chem Int Ed Engl. 2012 Mar 5;51(10):2371-4. doi: 10.1002/anie.201106748. Epub 2012 Jan 24.
The versatile octadentate TIAM ligand forms lanthanide (Sm, Eu, Tb, Dy, Ho) complexes with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.
多功能八齿 TIAM 配体在水中与镧系元素(Sm、Eu、Tb、Dy、Ho)形成高量子产率的配合物。该配体是一种有效的敏化剂,还可以保护金属中心免受溶剂猝灭,这一点通过对 Ho 配合物的 X 射线衍射研究得到了证实。