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一种用于在水中激发可见和近红外镧系元素发射器的单敏化剂,具有高量子产率。

A single sensitizer for the excitation of visible and NIR lanthanide emitters in water with high quantum yields.

机构信息

Department of Chemistry, University of California Berkeley, Berkeley, CA 94720-1460, USA.

出版信息

Angew Chem Int Ed Engl. 2012 Mar 5;51(10):2371-4. doi: 10.1002/anie.201106748. Epub 2012 Jan 24.

Abstract

The versatile octadentate TIAM ligand forms lanthanide (Sm, Eu, Tb, Dy, Ho) complexes with high quantum yields in water. This ligand is an efficient sensitizer, and also shields the metal center from solvent quenching, as shown by an X-ray diffraction study of the Ho complex.

摘要

多功能八齿 TIAM 配体在水中与镧系元素(Sm、Eu、Tb、Dy、Ho)形成高量子产率的配合物。该配体是一种有效的敏化剂,还可以保护金属中心免受溶剂猝灭,这一点通过对 Ho 配合物的 X 射线衍射研究得到了证实。

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