迈向多功能镧系基金属有机框架

Towards multifunctional lanthanide-based metal-organic frameworks.

作者信息

Tobin Gerard, Comby Steve, Zhu Nianyong, Clérac Rodolphe, Gunnlaugsson Thorfinnur, Schmitt Wolfgang

机构信息

School of Chemistry and Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), University of Dublin, Trinity College Dublin, Dublin 2, Ireland.

出版信息

Chem Commun (Camb). 2015 Sep 4;51(68):13313-6. doi: 10.1039/c5cc04928h.

DOI:10.1039/c5cc04928h

PMID:26207535

Abstract

We report the synthesis, structure and physicochemical attributes of a new holmium(III)-based metal-organic framework whose 3D network structure gives rise to porosity; the reported structure-type can be varied using a range of different lanthanide ions to tune the photophysical properties and produce ligand-sensitised near-infrared (NIR) and visible light emitters.

摘要

我们报道了一种新型钬（III）基金属有机框架的合成、结构及物理化学性质，其三维网络结构产生了孔隙率；通过使用一系列不同的镧系离子，可以改变所报道的结构类型，以调节光物理性质并产生配体敏化的近红外（NIR）和可见光发射体。