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有机和无机表面上水合作用的微观动力学的共同特征。

Common features in the microscopic dynamics of hydration water on organic and inorganic surfaces.

机构信息

Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA.

出版信息

J Phys Condens Matter. 2012 Feb 15;24(6):064104. doi: 10.1088/0953-8984/24/6/064104. Epub 2012 Jan 25.

Abstract

The microscopic dynamics of hydration water exhibits some universal features that do not depend on the nature of the hydrated surface. We show that the hydration level dependence of the dynamic transition in the mean squared atomic displacements measured by means of elastic neutron scattering is qualitatively similar for hydration water in inorganic and organic hosts. The difference is that the former are 'rigid', whereas the dynamics of the latter can be enhanced by the motions of the hydration water. The overall hydration level appears to be the main parameter governing the magnitude of the mean squared atomic displacements in the hydration water, irrespective of the details of the hydrated host.

摘要

水合作用中水分子的微观动力学表现出一些普遍特征,这些特征不依赖于水合表面的性质。我们表明,通过弹性中子散射测量的均方位移的动态跃迁对水合水平的依赖性在无机和有机主体中的水合作用中是定性相似的。不同之处在于前者是“刚性的”,而后者的动力学可以通过水合作用的运动来增强。总的水合水平似乎是控制水合水中均方位移大小的主要参数,而与水合主体的细节无关。

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