Liu Bo, Wang Guo-Xiang, Wang Feng-He, Du Xu, Ling Fen, Xia Jin
College of Geography Science, Nanjing Normal University, Nanjing 210046, China.
Huan Jing Ke Xue. 2011 Oct;32(10):2971-8.
Water and sediment samples were collected from a heavily polluted urban river in the Xianlin University Town of Nanjing. We examined the effects of different aeration ways (aerating to sediments, aerating to water) on migration and transformation of nitrogen, using the indoor experimental method. The results showed that: nitrogen release from sediments in the form of NH4(+) -N that will accumulate under anaerobic conditions with increasing temperature; the maximum accumulation of NH4(+) -N in overlying water showed that aerating to water group < aerating to sediment group < control group and the maximum concentrations reached 9.40 mg x L(-1), 11.24 mg x L(-1) and 19.30 mg x L(-1), respectively; nitrogen compounds were generally eliminated from experiment system by a process of ammonia volatilization and a combination of two processes, i. e. nitrification and denitrification under aerating conditions; aerating to sediment was more effective for nitrogen removal than aerating to water, which was removed from overlying water, pore water and sediment; at the experimental endpoint, the concentrations of NH4(+) -N in pore water and sediment were significantly decreased by 64.36% and 58.73% respectively compared with those before aeration in aerating to sediment group and that were decreased by 39.53% and 38.78% respectively in aerating to water group; during nitrogen transformation process in overlying water, start-up of nitrification was slowly under aerating conditions; it took 9 days to realize nitrification under aerating to water conditions and 16 days under sediment aeration conditions; the NO2(-) -N accumulation took place in overlying water under the condition of aeration; the sustain time of NO2(-) -N accumulating was 17 days in aerating to water group and that was 14 days in aerating to sediment group.
从南京仙林大学城一条重度污染的城市河流采集了水和沉积物样本。我们采用室内实验方法,研究了不同曝气方式(对沉积物曝气、对水体曝气)对氮迁移转化的影响。结果表明:沉积物中氮以NH4(+) -N形式释放,在厌氧条件下会随着温度升高而积累;上覆水中NH4(+) -N的最大积累量显示,水体曝气组 < 沉积物曝气组 < 对照组,最大浓度分别达到9.40 mg·L(-1)、11.24 mg·L(-1) 和19.30 mg·L(-1);在曝气条件下,氮化合物通常通过氨挥发以及硝化和反硝化两个过程的组合从实验系统中去除;对沉积物曝气比水体曝气对氮的去除更有效,氮从上覆水、孔隙水和沉积物中被去除;在实验终点,沉积物曝气组孔隙水和沉积物中NH4(+) -N的浓度分别比曝气前显著降低了64.36%和58.73%,水体曝气组分别降低了39.53%和38.78%;在上覆水氮转化过程中,曝气条件下硝化作用启动缓慢;水体曝气条件下实现硝化作用需要9天,沉积物曝气条件下需要16天;曝气条件下上覆水中会发生NO2(-) -N积累;水体曝气组NO2(-) -N积累的持续时间为17天,沉积物曝气组为14天。