State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P R China.
Dalton Trans. 2012 Mar 21;41(11):3138-40. doi: 10.1039/c2dt12238c. Epub 2012 Feb 3.
An enantioenriched three-dimensional quartz-type framework {[Ni(1.5)(tzdc)(H(2)O)(3)]·3H(2)O}(n) (H(3)tzdc = 4H-1,2,4-triazole-3,5-dicarboxylic acid) possessing chiral channels is obtained through spontaneous asymmetric crystallization without any enantiopure additive.
手性通道的三维石英型骨架配合物{[Ni(1.5)(tzdc)(H2O)(3)]·3H2O}(n) (H3tzdc = 4H-1,2,4-三唑-3,5-二羧酸) 通过自发不对称结晶获得,无需任何手性纯添加剂。