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控制合成纳米晶 Li2MnSiO4 颗粒,用于锂离子电池中高容量正极的应用。

Controlled synthesis of nanocrystalline Li2MnSiO4 particles for high capacity cathode application in lithium-ion batteries.

机构信息

Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Sendai 980-8577, Japan.

出版信息

Chem Commun (Camb). 2012 Mar 11;48(21):2698-700. doi: 10.1039/c2cc17234h. Epub 2012 Feb 3.

DOI:10.1039/c2cc17234h
PMID:22307175
Abstract

Monodispersed Li(2)MnSiO(4) nanoparticles are synthesized via a supercritical solvothermal method at 300 °C for 5 min reaction time. The as-synthesized nanoparticles are free from impurities and have 15-20 nm diameter. After coating with conductive polymer, a discharge capacity of 313 mA h g(-1) is obtained for the first time because of nearly 2Li(+) reaction.

摘要

通过在 300°C 下超临界溶剂热法反应 5 分钟,合成了单分散的 Li(2)MnSiO(4)纳米颗粒。所合成的纳米颗粒无杂质,直径为 15-20nm。经过导电聚合物包覆后,首次获得了 313 mA h g(-1)的放电容量,这是因为发生了近 2Li(+)反应。

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