Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Toronto, Ontario, M5S 3E5, Canada.
J Org Chem. 2012 Mar 2;77(5):2531-6. doi: 10.1021/jo202365x. Epub 2012 Feb 16.
The synthesis and study of a series of pseudohalides of boron subphthalocyanine (BsubPc) are reported. Each pseudohalide has been compared to the more common chloride and bromide of BsubPc, and we have found that most react slower under standard phenoxylation and hydrolysis conditions. Three pseudohalides (TsO-BsubPc, MsO-BsubPc, and BsO-BsubPc) do not hydrolyze at all even after prolonged periods of time in the presence of water. Single crystals of TsO-, MsO-, and ClsO-BsubPc were obtained, and their structures were unambiguously determined.
报道了一系列硼次酞菁（BsubPc）类假卤化物的合成与研究。将每种假卤化物与更为常见的 BsubPc 氯化物和溴化物进行了比较，发现大多数在标准苯氧基化和水解条件下反应更慢。三种假卤化物（TsO-BsubPc、MsO-BsubPc 和 BsO-BsubPc）即使在水中存在很长时间也根本不会水解。获得了 TsO-、MsO-和 ClsO-BsubPc 的单晶，并明确确定了它们的结构。
