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多壁氮化硼纳米管的径向弹性。

Radial elasticity of multi-walled boron nitride nanotubes.

机构信息

Department of Mechanical Engineering, State University of New York at Binghamton, Binghamton, NY 13902, USA.

出版信息

Nanotechnology. 2012 Mar 9;23(9):095703. doi: 10.1088/0957-4484/23/9/095703. Epub 2012 Feb 10.

Abstract

We investigated the radial mechanical properties of multi-walled boron nitride nanotubes (MW-BNNTs) using atomic force microscopy. The employed MW-BNNTs were synthesized using pressurized vapor/condenser (PVC) methods and were dispersed in aqueous solution using ultrasonication methods with the aid of ionic surfactants. Our nanomechanical measurements reveal the elastic deformational behaviors of individual BNNTs with two to four tube walls in their transverse directions. Their effective radial elastic moduli were obtained through interpreting their measured radial deformation profiles using Hertzian contact mechanics models. Our results capture the dependences of the effective radial moduli of MW-BNNTs on both the tube outer diameter and the number of tube layers. The effective radial moduli of double-walled BNNTs are found to be several-fold higher than those of single-walled BNNTs within the same diameter range. Our work contributes directly to a complete understanding of the fundamental structural and mechanical properties of BNNTs and the pursuits of their novel structural and electronics applications.

摘要

我们使用原子力显微镜研究了多壁氮化硼纳米管(MW-BNNTs)的径向机械性能。所使用的 MW-BNNTs 是使用加压蒸气/冷凝器(PVC)方法合成的,并在离子表面活性剂的辅助下通过超声分散在水溶液中。我们的纳米力学测量揭示了具有两个到四个管壁的单个 BNNTs 在横向方向上的弹性变形行为。通过使用赫兹接触力学模型解释它们测量的径向变形曲线,我们获得了它们的有效径向弹性模量。我们的结果捕获了 MW-BNNTs 的有效径向模量对管外径和管层数的依赖性。在相同的直径范围内,双壁 BNNTs 的有效径向模量被发现比单壁 BNNTs 高几个数量级。我们的工作直接有助于对 BNNTs 的基本结构和机械性能以及对其新颖的结构和电子应用的追求的完整理解。

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