Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Small. 2012 Apr 10;8(7):1060-5. doi: 10.1002/smll.201102070. Epub 2012 Feb 14.
Core-shell structured La(0.7) Sr(0.3) CoO(3) nanoparticles are synthesized and their magnetic and magneto-transport properties are investigated. In these core-shell La(0.7) Sr(0.3) CoO(3) nanoparticles, the cores are single-crystalline and ferromagnetic, whereas the shells are noncrystalline and predominantly paramagnetic. Moreover, the insulating-like shells can serve as a good spin tunneling barrier. Therefore, in such a special core-shell structure, the spin-polarized interparticle tunneling is improved due to the existence of shells, which thus induces an enhanced low-field magnetoresistance effect.
核壳结构的 La(0.7) Sr(0.3) CoO(3) 纳米颗粒被合成,并对其磁性和磁输运性质进行了研究。在这些核壳 La(0.7) Sr(0.3) CoO(3) 纳米颗粒中,核是单晶的且铁磁的,而壳是非晶的且主要是顺磁的。此外,绝缘样的壳可以作为一个良好的自旋隧道势垒。因此,在这种特殊的核壳结构中,由于壳的存在,自旋极化的颗粒间隧穿得到改善,从而导致增强的低场磁电阻效应。