金属诱导折叠：两种 44 元酰腙大环配体的镧系金属配合物的合成与构象分析。
Metal induced folding: synthesis and conformational analysis of the lanthanide complexes of two 44-membered hydrazone macrocycles.
机构信息
University Chemical Laboratory, University of Cambridge, UK.
出版信息
Dalton Trans. 2012 Apr 7;41(13):3780-6. doi: 10.1039/c2dt11861k. Epub 2012 Feb 15.
PMID:22334117
Abstract
Six new lanthanide complexes of two 44-membered macrocycles have been prepared and characterised in solution. An analysis of the conformations of the free macrocycles and their lanthanide complexes both in solution (2D NMR) and in solid state (X-ray crystallography) demonstrate that the complexation induces changes in folding of the macrocycles.
摘要
已经制备并在溶液中对两种 44 元大环的六个新镧系元素配合物进行了表征。对游离大环及其镧系元素配合物在溶液中的构象（二维 NMR）和固态（X 射线晶体学）的分析表明，配合作用会引起大环折叠的变化。
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