无金属芳香族加氢：苯胺到环己基-胺衍生物。
Metal-free aromatic hydrogenation: aniline to cyclohexyl-amine derivatives.
机构信息
Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
出版信息
J Am Chem Soc. 2012 Mar 7;134(9):4088-91. doi: 10.1021/ja300228a. Epub 2012 Feb 21.
PMID:22335795
Abstract
Hydrogenation of the N-bound phenyl rings of amines, imines, and aziridine is achieved in the presence of H(2) and B(C(6)F(5))(3), affording the corresponding N-cyclohexylammonium hydridoborate salts.
摘要
在氢气和 B(C(6)F(5))(3)的存在下，实现了胺、亚胺和氮杂环丙烷的 N-芳基环氢化，得到相应的 N-环己基铵氢硼酸盐。
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