College of Life Science & Bioengineering, Beijing University of Technology, Beijing 100124, China.
Org Lett. 2012 Mar 2;14(5):1314-7. doi: 10.1021/ol300195c. Epub 2012 Feb 16.
A new class of metal-free, easy to synthesize redox catalysts based on a triarylimidazole framework is described. With those synthesized thus far, one can access a potential range of ca. 410 mV. They proved to be useful mediators for the activation of benzylic C-H bonds under mild conditions.
描述了一类新型的无金属、易于合成的基于三芳基咪唑骨架的氧化还原催化剂。迄今为止，通过合成这些催化剂，可以获得约 410 mV 的潜在范围。它们被证明是在温和条件下激活苄基 C-H 键的有用介体。
