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钼酸铕（III）锂，Li(3.5)Eu(1.5)(MoO(4))(4)

Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4).

作者信息

Zhao Dan, Zhu Jing, Liang Peng, Chang Huan, He Rong

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):i14. doi: 10.1107/S1600536812000268. Epub 2012 Jan 11.

DOI:10.1107/S1600536812000268
PMID:22346790
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274837/
Abstract

The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Formula: see text]), distorted LiO(6) polyhedra and MoO(4) tetra-hedra, which are further inter-connected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner.

摘要

标题化合物Li(3.5)Eu(1.5)(MoO(4))(4)通过固相反应制备。该结构的基本构筑单元是LiO(4)多面体（点群对称性[化学式：见原文]）、扭曲的LiO(6)多面体和MoO(4)四面体，它们通过共用角顶的O原子进一步相互连接。一个位点被Li和Eu原子以取代无序的方式（0.25:0.75）占据，且Li/Eu原子以扭曲的四方反棱柱方式由八个O原子配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6632/3274837/e42ff5f8a9ea/e-68-00i14-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6632/3274837/83490bb5031b/e-68-00i14-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6632/3274837/e42ff5f8a9ea/e-68-00i14-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6632/3274837/83490bb5031b/e-68-00i14-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6632/3274837/e42ff5f8a9ea/e-68-00i14-fig2.jpg

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Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.