Zeng Ling, Wang Qinglin
College of Chemistry and Chemical Engineering of Bohai University, Jinzhou, Liaoning 121000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m196. doi: 10.1107/S1600536812001778. Epub 2012 Jan 21.
The asymmetric unit of the title compound, Zn(2)(C(2)O(4))(C(10)H(8)N(2))(2)(H(2)O)(4)(2)·6H(2)O, contains one half of the centrosymmetric binuclear cation, one anion and three water mol-ecules. In the cation, the oxalate ligand bridges two Zn(II) ions in a bis-bidentate fashion, so each Zn(II) ion is coordinated by two O atoms from the oxalate ligand, two N atoms from two 2,2'-bipyridine ligands and two water mol-ecules in a distorted octa-hedral arrangement. The mean planes of the oxalate and 2,2'-bipyridine ligands form a dihedral angle of 80.0 (1)°. An extensive three-dimensional hydrogen-bonding network formed by classical O-H⋯O and O-H⋯N inter-actions consolidates the crystal packing.
标题化合物Zn₂(C₂O₄)(C₁₀H₈N₂)₂(H₂O)₄₂·6H₂O的不对称单元包含一个中心对称双核阳离子的一半、一个阴离子和三个水分子。在阳离子中,草酸根配体以双齿方式桥连两个Zn(II)离子,因此每个Zn(II)离子由草酸根配体的两个O原子、两个2,2'-联吡啶配体的两个N原子以及两个水分子以扭曲八面体构型配位。草酸根和2,2'-联吡啶配体的平均平面形成80.0 (1)°的二面角。由经典的O—H⋯O和O—H⋯N相互作用形成的广泛三维氢键网络巩固了晶体堆积。