Zeng Ling
College of Chemistry and Chemical Engineering of Bohai University, Jinzhou, Liaoning 121000, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m329. doi: 10.1107/S1600536812007404. Epub 2012 Feb 24.
In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra-molecular O-H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol-ecules and water mol-ecules are connected by O-H⋯O and O-H⋯N hydrogen bonds to generate a three-dimensional network.
在水合标题配合物[Mn(C₈H₆N₃O₂)(CH₃CO₂)(C₁₂H₈N₂)(H₂O)₂]·2H₂O中，Mn(II)原子由1,10 - 菲咯啉配体的两个N原子、两个水分子的O原子、一个单齿乙酸根阴离子和一个O - 单齿2-(1H - 苯并三唑 - 1 - 基)乙酸根配体配位，形成扭曲的顺式 - MnN₂O₄八面体配位几何构型。水分子的O原子呈反式排列，其中一个与乙酸根离子未配位的O原子形成分子内O - H⋯O氢键。在晶体中，配合物分子和水分子通过O - H⋯O和O - H⋯N氢键相连，形成三维网络。
