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链状聚[[[双-[[μ-3-(4-羧基苯氧基)丙酸根合]-κO,O:O;κO:O,O-双-[水合-(N,N-二甲基甲酰胺-κO)镉]]-μ-4,4'-联吡啶-κN:N']二硝酸酯]

catena-Poly[[[bis-[μ-3-(4-carb-oxy-phen-oxy)propionato]-κO,O:O;κO:O,O-bis-[aqua-(N,N-dimethyl-formamide-κO)cadmium]]-μ-4,4'-bipyridine-κN:N'] dinitrate].

作者信息

Gao Shan, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m214. doi: 10.1107/S1600536812002991. Epub 2012 Jan 31.

Abstract

In the title coordination polymer, {Cd(2)(C(10)H(9)O(5))(2)(C(10)H(8)N(2))(2)(C(3)H(7)NO)(2)(H(2)O)(2)(2)}(n), the 3-(4-carb-oxy-phen-oxy)propionate monoanion O,O'-chelates to a Cd(II) cation through the aliphatic carboxyl-ate end. One of these O atoms is also connected to the metal cation from an inversion-related metal atom. The five O atoms bonded to the metal centre form a penta-gon, above and below which are located the N atoms of the 4,4'-bipyridine mol-ecules. The polycationic ribbon propagates along the b axis of the unit cell. The (aromatic) carboxyl end of the monoanion connects adjacent ribbons into a layer motif in the (102) plane. The nitrate ions are hydrogen bonded to the layer. The geometry of the Cd(II) atom is a trans-N(2)O(5)Cd penta-gonal bipyramid.

摘要

在标题配位聚合物{Cd₂(C₁₀H₉O₅)₂(C₁₀H₈N₂)₂(C₃H₇NO)₂(H₂O)₂₂}ₙ中,3-(4-羧基苯氧基)丙酸根单阴离子通过脂肪族羧酸根末端与一个Cd(II)阳离子形成O,O'-螯合。其中一个O原子还与一个来自反演相关金属原子的金属阳离子相连。与金属中心键合的五个O原子形成一个五边形,在其上方和下方是4,4'-联吡啶分子的N原子。聚阳离子带沿晶胞的b轴延伸。单阴离子的(芳香族)羧基末端将相邻的带连接成(102)平面中的层状结构。硝酸根离子通过氢键与该层相连。Cd(II)原子的几何构型为反式-N₂O₅Cd五角双锥。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/22b8/3274930/c704e713b424/e-68-0m214-fig1.jpg

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