Deng Zhao-Peng, Gao Shan, Ng Seik Weng
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m225. doi: 10.1107/S160053681200339X. Epub 2012 Jan 31.
The reaction of silver nitrate with 5-chloro-2-hy-droxy-benzene-sulfonic acid in the presence of ammonia yielded the title salt, (NH(4))Ag(NH(3))(2)(2)·3H(2)O. The Ag(I) ion shows linear coordination [N-Ag-N = 175.2 (1) °]. The ammonium and diamminesilver cations, the benzene-sulfonate anion and the lattice water mol-ecules inter-act through an intricate network of N-H⋯O and O-H⋯O hydrogen bonds to form a three-dimensional network.
硝酸银与5-氯-2-羟基苯磺酸在氨存在下反应生成标题盐(NH₄)Ag(NH₃)₂₂·3H₂O。Ag(I)离子呈直线型配位[N-Ag-N = 175.2 (1)°]。铵根和二氨合银阳离子、苯磺酸盐阴离子以及晶格水分子通过复杂的N-H⋯O和O-H⋯O氢键网络相互作用,形成三维网络。