Leka Zorica, Novaković Sladjana B, Stevanović Dragana, Bogdanović Goran A, Vukićević Rastko D
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m230. doi: 10.1107/S1600536812003509. Epub 2012 Jan 31.
In the title ferrocene derivative, [Fe(C(5)H(5))(C(15)H(16)NO)], the dihedral angle between the best planes of the benzene and the substituted cyclo-penta-dienyl ring is 83.4 (1)°. The presence of a methyl substituent in the para position of the aniline group does not alter the crystal packing compared to that of 3-anilino-1-ferrocenylpropan-1-one [Leka et al. (2012 ▶). Acta Cryst. E68, m229]. The molecules are connected into centro-symmetric dimers via N-H⋯O hydrogen bonds. In addition, C-H⋯O and C-H⋯N contacts stabilize the crystal packing.
在标题二茂铁衍生物[Fe(C₅H₅)(C₁₅H₁₆NO)]中，苯环与取代环戊二烯基环的最佳平面之间的二面角为83.4 (1)°。与3-苯胺基-1-二茂铁基丙-1-酮[Leka等人（2012年▶）。Acta Cryst. E68, m229]相比，苯胺基团对位甲基取代基的存在并未改变晶体堆积。分子通过N-H⋯O氢键连接成中心对称二聚体。此外，C-H⋯O和C-H⋯N接触使晶体堆积得以稳定。
