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1,4-二丁氧基-2,5-双-{（Z）-2-[4-（9H-咔唑-9-基）苯基]乙烯基}苯

1,4-Dibut-oxy-2,5-bis-{(Z)-2-[4-(9H-carbazol-9-yl)phen-yl]ethen-yl}benzene.

作者信息

Fei Wen-Wen, Li Rui, Wang Zhen-Yu, Wu Jie-Ying

机构信息

Department of Chemistry, Anhui University, Hefei 230039, People's Republic of China, and Key Laboratory of Functional Inorganic Materials Chemistry, Hefei 230039, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o321. doi: 10.1107/S1600536812000414. Epub 2012 Jan 11.

DOI:10.1107/S1600536812000414
PMID:22346955
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3275010/
Abstract

The title compound, C(54)H(48)N(2)O(2), lies about an inversion centre. The carbazole ring system makes dihedral angles of 58.43 (7) and 88.96 (7)°, respectively, with the adjacent and central benzene rings. The dihedral angle between the two benzene rings is 52.01 (8)°. In the crystal, mol-ecules are linked by pairs of C-H⋯O inter-actions, forming a tape along the a axis. The methyl group is disordered over two sets of sites with occupancies of 0.63 (3) and 0.37 (3).

摘要

标题化合物C(54)H(48)N(2)O(2)位于一个对称中心上。咔唑环系统与相邻苯环和中心苯环的二面角分别为58.43 (7)°和88.96 (7)°。两个苯环之间的二面角为52.01 (8)°。在晶体中，分子通过C—H⋯O相互作用对连接，沿a轴形成一条链。甲基在两组位置上无序分布，占有率分别为0.63 (3)和0.37 (3)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c257/3275010/c5eaeef37557/e-68-0o321-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c257/3275010/c5eaeef37557/e-68-0o321-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c257/3275010/c5eaeef37557/e-68-0o321-fig1.jpg

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本文引用的文献

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