Madhanraj R, Murugavel S, Kannan D, Bakthadoss M
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o418-9. doi: 10.1107/S1600536812000864. Epub 2012 Jan 14.
In the title compound, C(25)H(25)NO(5)S, the O atom of the hy-droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy-droxy-methyl-benzene and phenyl rings. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.
在标题化合物C₂₅H₂₅NO₅S中,羟基的O原子在两个位置上无序,占有率分别为0.820 (2) 和0.180 (2)。磺酰基连接的苯环分别与羟甲基苯环和苯环形成31.8 (1)°和60.7 (1)°的二面角。分子构象通过分子内O—H⋯O氢键得以稳定,形成S(8)环模式。晶体堆积通过分子间C—H⋯O氢键和C—H⋯π相互作用得以稳定。