Yoon Yeong Keng, Ali Mohamed Ashraf, Wei Ang Chee, Asik Safra Izuani Jama, Razak Ibrahim Abdul
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o471-2. doi: 10.1107/S1600536812001420. Epub 2012 Jan 21.
In the title compound, C(24)H(25)N(3)O(5), the benzimidazole and benzodioxole ring systems are each approximately planar [maximum deviations = 0.043 (1) and 0.036 (1) Å, respectively]. Their mean planes form a dihedral angle of 42.85 (4)°. The pyrrolidine ring has an envelope conformation with one of the methyl-ene C atoms forming the flap. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. The crystal packing is further stabillized by weak π-π inter-actions between the benzene rings within the benzimidazole ring system [centroid-centroid distance = 3.7955 (7) Å]. A weak C-H⋯π inter-action involving the benzodioxole ring is also present.
在标题化合物C₂₄H₂₅N₃O₅中,苯并咪唑和苯并二氧杂环系统各自近似平面[最大偏差分别为0.043 (1) 和0.036 (1) Å]。它们的平均平面形成42.85 (4)°的二面角。吡咯烷环具有信封式构象,其中一个亚甲基C原子形成瓣。在晶体中,弱的C—H⋯O氢键将分子连接成三维网络。苯并咪唑环系统内苯环之间的弱π-π相互作用[质心-质心距离 = 3.7955 (7) Å]进一步稳定了晶体堆积。还存在涉及苯并二氧杂环的弱C—H⋯π相互作用。